I think he has convinced you that he is really skilled and you are interpreting everything in that light - i.e. confirmation bias. At the moment you seem to be trying things at random that you have heard of (trying a different browser, two routers, switching from Android to Apple). You need to calm down and re-evaluate and then get some advice.
This!
I find this thread fascinating because our
@estwig is obviously being gaslighted by a classic narcissist. Yes, this does lead to paranoia and one starts to imagine all kinds of things that actually have nothing to do with the stalker. That's part of the gaslighting process.
But there are things you can do to mitigate the whole situation - starting with getting rid of all the useless and pointless toys you have accumulated such as smartphones and heating systems that can be activated remotely. As for the idea that your stalker is placing trackers on your car - I very much doubt it when there are so many other ways to track a person, especially one that insists on taking a mobile phone with them everywhere they go!
But this mania you seem to have for connecting everything to everything else has to stop. Nobody on Planet Earth needs to have a heating system or indeed any other household device connected to anything - that's asking for trouble. Also, your heating system should be turned off when not in use - and I mean turned off at the mains!
When you go to bed, turn the whole interweb and all phones off at the mains.
Deactivate all LANs. If you want to move data, either FTP it or stick it on a stick or SSD instead.
Get a cheap anonymous burner phone with a new number if you insist on having a phone with you at all times.
Never ever store passwords anywhere other than handwritten and on a piece of paper!
Never ever install or use anything with voice commands, such as Alexa or any of the other useless connected toys being pushed today (nothing to do with your stalker, but everything to do with your privacy!)
You have been given some excellent advice here by
@Nico Albrecht on how to harden your systems.
And stop ascribing this idiot stalker of yours with superhuman powers. It reminds me of when I was a kid, I learned how to pick locks - it was easy because they all work the same way with simple pins or tines and barriers. But all my buddies thought I was some lock-picking genius because I created a passkey for our whole school.
Well, your Captain Genius here is doing the same thing - using some simple way into your over-connected household and it's probably something he did whilst you two were still together.
(If you really want to have fun, get someone who is a real expert and knows how to create a virtual PC with a Trojan Horse that wipes his system, inc. all smartphones.)