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Charge cards just ensure the balance is cleared in full at the end of the month... would you not want that?
If you provide staff with a credit card for out of pocket expenses, don't forget you'll need to report this in the appropriate section of each person's P11D unless you have a dispensation (I'm not sure you can get a dispensation for credit card payments though). They will need to keep their receipts and apply for tax relief on allowable business expenses to avoid being taxed (via a tax code adjustment normally).
I don't have any staff but have one of these for company expenses:
http://www.barclays.co.uk/Paymentservices/Businesscreditcards/P1242558528990
Do they not just let me have the receipts and I then put them through the books and then it is all done and dusted